Plastic waste is
accumulated in landfills and the environment at an exponentially increasing rate.
Currently, about 350 million tons of plastic waste is generated annually while only
9% is recycled. Plastic waste and its degradation products, microplastics, pose
a severe threat to the ecosystem and eventually human health. Polyolefin (Polyethylene
(PE) and Polypropylene (PP)) waste is 63% of the total plastic waste. Converting
polyolefin waste into useful products including clean gasoline, diesel, wax,
and monomers, via hydrothermal processing (HTP) can help reduce the plastic
waste accumulation. In this study, sorted PE waste was converted via
supercritical water liquefaction (SWL) into gasoline blendstock, No.1
ultra-low-sulfur diesel, and clean waxes with high yields and high purities.
Comprehensive reaction pathways for PE conversion were proposed based on
detailed GC×GC analyses. Furthermore, a new low-pressure (~2 MPa) hydrothermal
processing (LP-HTP) method was developed to convert mixed polyolefin waste. This
new LP-HTP method can save 90% of the capital cost and energy compared to SWL.
The oil products were distilled into clean gasoline and No.1 ultra-low-sulfur
diesel. The reaction pathways of PE and PP were independent while the synergistic
effects improved the fuel qualities. With this LP-HTP method, polyolefin waste
can be converted into up to 190 million tons of fuels globally, while 92% of
the energy and 71% of the GHG emissions can be saved compared to conventional
methods for producing fuels. Overall, this method is robust, flexible,
energy-efficient, and environmental-friendly. It has a great potential for
reducing the polyolefin waste accumulation in the environment and associated
risks to human health.
Funding
School of Engineering Technology at Purdue University
Davidson School of Chemical Engineering at Purdue University
Trask Innovation Fund from the Purdue Research Foundation