Chapter 3

Reason: One paper with data of chapter 3 is under revision for a peer-reviewed journal.

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KINETICS AND APPLICATIONS OF ON-SURFACE TOPOCHEMICAL POLYMERIZATION OF DIACETYLENE STRIPED PHASES

thesis
posted on 25.04.2022, 16:05 authored by Anni ShiAnni Shi

Here presents the studies of polymerization kinetics and crosslinking efficiency of nm-resolution striped phases on surface, which depends on lengths of alkyl segments and headgroup chemistry. While fluorescence readouts offer the overall efficiencies of polymerization and crosslinking transfer, SPM measurements reveal molecular details accounting for reactivity differences. Additionally, this research also demonstrates the utilization of primary amines striped phases on soft materials, achieving post-functionalization and specific  adsorption of nanocrystals, highlighting the versatile applications of this nm-scale chemistry boundary.

Funding

Precision Monolayer Chemistry on Amorphous Materials

Directorate for Mathematical & Physical Sciences

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History

Degree Type

Doctor of Philosophy

Department

Chemistry

Campus location

West Lafayette

Advisor/Supervisor/Committee Chair

Shelley A. Claridge

Additional Committee Member 2

Christina W. Li

Additional Committee Member 3

Suzanne C. Bart

Additional Committee Member 4

Chi Zhang

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