Purdue University Graduate School
DeLange_Thesis (1).pdf (119.99 MB)

Optical Properties of Rydberg Excitons in Cuprous Oxide

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posted on 2023-04-12, 13:51 authored by Jacob C DeLangeJacob C DeLange

Cuprous oxide (Cu2O) has recently been proposed as a promising solid-state host for ex-
citonic Rydberg states with large principal quantum numbers (n) whose exaggerated wave-
function sizes (∝ n2) facilitate gigantic, resonant dipole-dipole (∝ n4) and van der Waals
(∝ n11) interactions, making them an ideal basis for solid-state Rydberg physics and quan-
tum technology. Synthetic, thin-film Cu2O samples are of particular interest because they
can be made defect-free via carefully controlled fabrication and are, in principle, suitable
for the observation of extreme single-photon nonlinearities caused by Rydberg blockade. In
this work, we present the development of a spectroscopy experiment for characterizing the
behavior of Rydberg excitons and use it to study a synthetic thin film of Cu2O grown on a
transparent substrate. We present evidence for the presence of states up to n = 8 and conduct
the first temperature-dependent study of Rydberg excitons in a thin film. We also propose
a technique for studying Rydberg-Rydberg interactions via the creation of high exciton den-
sities and establish a set of rate equations for modeling the processes by which excitons are
created, interact with each other, and decay. Finally, we conclude with a discussion of the
project’s outlook, as well as what future work will be undertaken to study the interactions
between Rydberg excitons and utilize them in scalable, integrable, Rydberg-based quantum


Purdue Military Research Initiative (PMRI)


Degree Type

  • Master of Science


  • Physics and Astronomy

Campus location

  • West Lafayette

Advisor/Supervisor/Committee Chair

Hadiseh Alaeian

Additional Committee Member 2

Chris Greene

Additional Committee Member 3

Libai Huang

Additional Committee Member 4

Qi-Yu Liang

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